Inductively Coupled Plasma-Mass Spectrometry

Inductively Coupled Plasma-Mass Spectrometry (ICP) is a powerful technique of chemical characterization capable of simultaneously measuring up to 50 different trace elements, sometimes at concentrations as low as several parts per billion.  The ICP-MS functions by passing small amounts of material into a plasma, a super-heated gas, which ionizes the sample material.   The plasma itself operates at around 8000 degrees C, a temperature greater than the surface of the sun.  This ionized sample is then sent through a series of powerful magnets called a mass spectrometer, which separates sample ions on the basis of their mass/charge ratio.  These ions are then measured by a detector to establish sample composition. 

Sample can be introduced into the ICP-MS either as a vaporized solid, or as a liquid.  One such method is Laser Ablation, in which a pulsed laser is used to remove small amounts of sample material, which is then swept into the plasma via a Helium carrier gas.  Alternatively, samples can be dissolved in solution and sent into the plasma in liquid form.  Depending on sample composition, this may involve dissolving the sample in strong acids, assited by high heat and pressure produced by bombarding the sample with microwaves.  Our Inductively Coupled Plasma Mass Spectrometry (ICP-MS) Laboratory operates around a high sensitivity Varian quadrupole ICP-MS and a New Wave UP213 laser ablation system for solid sample introduction.  Additionally, the ICP-MS laboratory houses a Milestone microwave digestion system for sample dissolution and liquid sample introduction.

 

The EAF ICP-MS laboratory.  The Varian ICP-MS is connected to our adaptable chamber UP266 laser ablation system, with a ceramic vessel from the north coast of Papua New Guinea positioned for analysis.

Laser Ablation is particularly valuable due to its ability to target specific components of samples.  For ceramics, it is possible to target paste, paints, temper, slips, and glazes separately.   In one study performed by museum scientists, the glazes on Chinese Blue and White porcelains and Celadon wares were analyzed chemically by LA-ICP-MS.  This study demonstrated that the majority of such ceramics found at archaeological sites in western India and eastern Africa were produced by Chinese kilns, and were not imitation wares produced at Middle Eastern or southeast Asian kilns.  Other projects have studied production and exchange of ceramics from Belgian Neolithic sites, proto-historical and historical archaeological sites in the Phillippines, Chinese Neolithic sites, ceramics on the northern coast of Papua New Guinea, and archaeological ceramics from throughout the central Andes.  Likewise, LA-ICP-MS can be used to analyze metal and corrosion products separately on metal artifacts, eliminating problems that have plagued bulk characterization studies of archaeological metals.  LA-ICP-MS is also highly useful for rapidly characterzing obsidian and artificial glasses.  The EAF has large ongoing projects applying LA-ICP-MS to characterize glass beads traded in the Indian Ocean, and obsidian from archaeological sites in the western Pacific, Andes, and Belize.

The EAF also houses a modified adaptable chamber New Wave UP266 laser ablation system developed in collaboration with Dr. Richard Cox at the University of Quebec at Chicoutimi, Canada.  This adaptable chamber laser ablation system is the first of its kind applied in a museum setting, having only been employed in experimental industrial systems previously.  As such, it equips the Field Museum with unique, virtually non-destructive, high precision, multi-element analysis for large objects that cannot be destructively subsampled, such as complete ceramic vessels.  Ongoing projects using the adaptable chamber to analyze collections objects include analysis of glass objects from the Sumerian city of Kish, and analysis of ceramics from the western Pacific.